Date of Award
3-14-2014
Document Type
Thesis
Degree Name
Master of Science
Department
Department of Engineering Physics
First Advisor
Timothy W. Zens, PhD.
Abstract
A non-destruction evaluation of atomically thin hexagonal boron nitride (h-BN) films is critical to the U.S. Air Force and Department of Defense initiatives pursuing graphene-based electronic field effect transistors (FETs) capable of operating at terahertz frequencies. H-BN thin films an increase to the characteristic E2g 1367cm-1 h-BN peak intensity has been correlated to an increase in film thickness. Raman spectroscopy on a h-BN film with thicknesses of 7, 14, and 21 atoms (2.5nm, 5nm, 7.5nm respectively) revealed a linear relationship between peak intensity and thickness. This relationship can mathematically be described as y=0.0265x+0.8084, and fits the data with a R2 value of 0.9986. There was no observed correlation between film thickness and full width at half maximum (FWHM) and there was no measured shift to the E2g peak with increasing film thickness.
AFIT Designator
AFIT-ENP-14-M-02
DTIC Accession Number
ADA598330
Recommended Citation
Bondy, James M., "Structural Characterization of Atomically Thin Hexagonal Boron Nitride via Raman Spectroscopy" (2014). Theses and Dissertations. 640.
https://scholar.afit.edu/etd/640